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Rackable was founded in 1999 and has been providing rack-mount server systems for years. It was not much of a stretch for them to quickly move into the blade space and gain the rank of fifth in the blade market (according to IDC).

100 Transmittance (%) 80 60 40 20 0 10

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The existence of the exchange current was clearly demonstrated by Pleskov and Miller on experiments with a solution containing metal ions labelled with a radioactive isotope. The solution was in contact with a dilute unlabelled amalgam of the same metal. The electrode reaction (proceeding in absence of an external voltage imposed on the metal) involved exchange of the labelled ions for unlabelled atoms in the amalgam. The rate of enrichment of the amalgam by the labelled isotope and its dependence on the concentrations of the solution and amalgam were completely in agreement with the relationship derived for the exchange current (5.2.26). The experiments were carried out under strong stirring, to suppress the effect of diffusion on the rate of the electrode process. An electrode reaction in which the oxidized form accepts more than one electron usually proceeds as a series of one-electron reaction steps. As will be demonstrated below, if the formal potentials of these partial electrode reactions satisfy certain conditions, then the electrode reaction simulates the transfer of several electrons in one step (Eq. 5.2.5) and obeys Eq. (5.2.24). An example is the two-electron reaction of substance Au converted to substance A3 by the transfer of two electrons, where the reaction occurs through the unstable intermediate A2: A, + e *=^ A2

40 50 Temperature ( C) (b)

Known for their ultradense rack solutions, Rackable leveraged this capability in creating their Scale Out Series of blade solutions.

(5.2.39) (5.2.40)

Figure 7.3. Effect of CD host guest interaction on azobenzene-modi ed polymers. (a) Drawing of the equilibrium between bound and unbound CDs. With the change of geometry under the cis form approaching the CD toward the backbone, Ktrans may be higher than Kcis. (b) Experimental variation of turbidity and shift of LCST measured in mixtures of hydroxypropyl methylcellulose in the presence or absence of aCD as quoted in the gure. Source: Reprinted with permission from Zheng et al., 2004.

263 The charge transfer reaction (5.2.39) is characterized by the formal electrode potential ', the conditional rate constant of the electrode reaction kf and the charge transfer coefficient ocly while the reaction (5.2.40) is characterized by the analogous quantities E2', kf and a2. If the rate constants of the electrode reactions, which are functions of the potential, are denoted as in Eqs (5.2.39) and (5.2.40) and the concentrations of substances A l5 A2 and A3 are cu c2 and c3, respectively, then - - = kc,\C\ + kcac2 - kalc2 - kaac3 (5.2.41) r The concentration of the unstable intermediate A2 is obtained from the steady-state condition, dc2 = 0 = kcAcx - kcac2 - kaJc2 + kaac3 Substitution for c2 in Eq. (5.2.41) yields J

Rackable has created something of a hybrid between rack-mount servers and blades. Rather than putting the blades vertically in a chassis, the Scale Out Series uses a standard rack to hold horizontal blades in a patented side-to-side and back-to-back configuration to support up to 88 blades (176 processors or 352 cores) per rack (see Figure 16.5). The rack holds two blades next to each other (side-to-side) in the front and two blades next to each other in the back (back-to-back). This design allows Rackable to use readily available processors and components, lowering their cost to build and maintain the systems (enabling them to pass those reductions on to customers). All power and cooling for the solution is distributed through the center of the rack, which uses a wired backplane of GbE, 100baseT, or serial interconnects. Power is shared throughout the rack via a bridge rectifier that converts AC power to DC, then it is distributed on a shared bus.

more hydrophilic than the cis one, presumably because of the deeper penetration of the E-form inside the CD cavity. Consequently, the coef cient aUV atrans in Equation 7.1 can become negative. In such mixed systems, the rst stage of ampli cation is achieved by recognition of azobenzene s isomers at the molecular scale. The second ampli cation stage is brought by chain collapsing in poor solvent. The development of new photocomplexing agents coupled with chain collapsing could certainly help design systems with a large temperature range of photoresponsiveness.

(5.2.42)