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Founded in 2000, Egenera started with a focus on mission-critical applications while other start-ups were focused on replacing rack servers for scale-out web services. The first BladeFrame shipped in late 2001 and went into production in early 2002 at Credit Suisse. Egenera continues to focus on large enterprise, service-provider, and government data centers. The company is small and privately held, with more than $150 million in funding as of 2006. Investors include Goldman Sachs, Credit Suisse, Austin Ventures, Lehman Brothers, Pharos Capital, Fujitsu Siemens Computers, and others. Egenera has a large number of partners, including technology, OEM, and reseller relationships. Most significantly, in 2005 they closed a $300 million OEM agreement with Fujitsu Siemens Computers, granting Fujitsu Siemens exclusive sales rights in Europe, the Middle East, and Africa. Egenera also worked with Liebert to jointly develop an extended cooling offering called CoolFrame, which adds a set of fans/radiators over the back of the BladeFrame Processor blades to capture heat and move it through tubing (out the top) to a Liebert XDP refrigerant-based coolant system. This option is sold and maintained by Liebert.

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The basic origins of photovariation of LCST are the photomodulation of hydrophobic binding and Van der Waals interactions. To enhance the effect (at xed degree of modi cation with azo, i.e., to achieving larger a values) it is possible to optimize the effect of isomerization on the chromophore chromophore (attractive) interaction and the chromophore-water (repulsive) interaction. The energy of hydrophobic association is certainly dif cult to estimate, but should depend mainly on the number of carbon atoms that can be transferred in apolar microdomains. If the azos are fully accessible in the modi ed polymers (e.g., exible chains, long spacers), the isomerization does not markedly affect the hydrophobic binding. In contrast, the E Z conversion modi es the dipole interactions to an extent that should vary in proportion to the dipole moments of E and Z forms (irrespective of polymer composition), making thus the aUV atrans coef cient in Equation 7.1 proportional to the dipole variation. We remark that almost optimal photoswitches of dipolar interaction have been reached in the published investigations, because the azobenzenes used were essentially apolar under their trans form and polar under their cis form. Improvements are therefore not obvious, and shall be devised on new basis, for instance, using additional enthalpic contributions to the intrachain interaction.

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(5.2.37)

Egenera is a great example of innovation coming from outside the ranks of the big players. The PAN architecture brings flexibility to the allocation and management of processors in much the way that SANs have for storage. Forwardthinking customers understand the value of this innovation and have been very pleased with their implementations, including some extremely large, mission-critical applications. The BladeFrame offering is a great example of the combination of blades and virtualization as building blocks for the next generation of data centers. Although other system vendors such as IBM and HP have evolved their product lines to include some similar functionality, Egenera has proven itself a strong and innovative player in this market and is well worth considering for a high-availability enterprise solution.

Typical attempts at enhancing the impact of E Z conversion on intrachain and monomer-solvent interactions use solution of CDs in water. CDs form host guest inclusion complexes with azobenzene derivatives (Zheng et al., 2002; Sanchez and deRossi, 1996; Yang et al., 1996; Suzuki et al., 1991). The association with CDs of azobenzene-containing chains adds further degrees of complexity (interaction between CDs and nonazo monomers can be attractive or repulsive) to the intrachain interactions. The association of CDs with the chain may depend on the E Z isomerisation. It was found that aCD and bCDs are best suited than larger CDs to discriminate the E and Z isomers of azobenzene. Naturally, the association of CD modi es the enthalpy of chain folding and collapsing, by masking the hydrophobes in CD cavities, and adding CD-monomers contacts and steric hampering to conformational freedom. All these effects contribute to chain swelling or collapse. The common interpretation of photoresponses in the presence of CDs invokes that the trans isomer associates tightly into the CD cavities, whereas the cis isomer does not bind (Zheng et al., 2004; RodriguezCabello et al., 2002; Ueno et al., 2002). Measurements by NMR and circular dichroism validate this point in some systems containing aCD (Tomatsu et al., 2006; Zheng et al., 2005). In general, things are less obvious, and CDs (especially bCD) may partially dissociate upon transconversion to the cis form, or bind to both the E and Z forms of azobenzene, with a different geometries and stoichiometries (Fig. 7.3a; Inoue et al., 2007; Pouliquen et al., 2007; Tomatsu et al., 2006). Both phenomena make nevertheless the azo-modi ed chains more hydrophilic in presence of CDs (upper shift of LCSTs). The dark-adapted (trans) form is even

The quantity /cconv = k ~ txp(anFEOt/RT) is the value of the rate constant of the electrode reaction at the potential of the standard reference electrode and will be termed the conventional rate constant of the electrode reaction. It can be found, for example, by extrapolation of the dependence (5.2.36) to E = 0, as

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