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Plotting the overpotential against the decadic logarithm of the absolute value of the current density yields the Tafel plot' (see Fig. 5.3). Both branches of the resultant curve approach the asymptotes for \ri\ RT/F. When this condition is fulfilled, either the first or second exponential term on the right-hand side of Eq. (5.2.28) can be neglected. The electrode reaction then becomes irreversible (cf. page 257) and the polarization curve is given by the Tafel equation = a+b\og\j\ (5.3.32)

16

Subsequently, photoinduced birefringence and surface relief structures have been reported in a photosensitive supramolecular material obtained by the ISA of poly(1-ethylvinylpyridinium bromide) and of commercially available azobenzene dye Methyl Orange (Xiao et al, 2007), as shown in Fig 210 However, a different mechanism of relief formation reported by the authors has to be stressed here The complex has a rigid molecular structure because of the absence of a spacer between the main chain and azobenzene unit and exhibits a lamellar organization with a periodicity of 27 nm Within this lamellar self-assembly, the disordered polyelectrolyte soft segments were alternated by the stacking of the Methyl Orange rigid side chain Laser-induced periodic surface structures (LIPSS) have been formed upon irradiation with an s-polarized beam of a pulsed UV laser operating at the wavelength of 355 nm if the intensity was high enough.

-200-

The period of the relief structure was strongly dependent on the incident angle of the laser beam At a period of about 400 nm, a relief depth of 100 nm was attained Formation of LIPSS was considered to be a result of thermal-induced macroscopic mass movement of molecules The high thermal stability of the induced.

number of components required with traditional servers by up to 80% According to Egenera, one customer with traditional servers counted more than 8,000 manageable components before moving to BladeFrames, and as a result of the move, reduced that number of components to 500 The PAN architecture is based on shared pools of resources, down to the processor level Each Processor blade (pBlade) contains only processors and memory, with no NICs or HBAs and no storage These blades communicate across the BladeFrame high-speed interconnect to redundant Control blades (cBlades), which contain a smaller number of shared network adapters (NICs and/or HBAs), with typically two to four of each per BladeFrame, rather than one or two per blade (The number of ports can be expanded up to 16 if needed, depending on the frame.

- 1 0 0\ N \

relief structures up to 1301C is noticeable The complex itself was stable at least up to 2751C The surfaces with LIPSS were used to align liquid crystals It should be commented here that probably the mechanism of LIPSS formation is different from the light-induced mass transport discussed in this chapter The authors investigated neither the induction of relief structures upon modulated irradiation nor the light reversibility of LIPSS, which makes it dif cult to compare these results Recently, the inscription of SRG in a similar dye polyelectrolyte spacer-free ionic complex shown in Fig 210 has been reported (Zhang et al, 2008) Although there is no spacer between the azobenzene unit and polymer chain, the material exhibits liquid crystalline SmA order SRGs with a grating spacing of 1 mm were induced in a 5- to 10-mm thick lm using rather low irradiation intensities of 65 mW/cm2 (Zhang et al.

^ / /

) Processor blades are completely stateless not only in terms of being diskless, but also by not being tied to MAC addresses or World Wide Names and are managed as a shared virtual pool through the Control blade (Egenera has filed for patents on this technology) This allows each type of component to be managed as a pool processor and memory components, shared networking adapters, and shared external storage (through a SAN) In addition to simplifying the environment and improving manageability, it also helps improve the speed of provisioning for both users and service providers Processor blades are offered in more than 20 combinations with both Intel and AMD chips, from single-core two-sockets with 2GB of memory, through dual-core, four-sockets with 32GB of memory and either 32- or 64-bit addressing There is a maximum of 24 blades per BladeFrame chassis (see Figure 164).