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, 2008; supporting information) The surface modulation depth approached 200 nm after 225-h irradiation The photoinduced birefringence in this material has been reported to be both temporally and thermally stable, but the authors did not comment on the thermal stability of the induced SRG The polarization dependence of the grating inscription, especially interesting in the case of liquid crystal material, was not commented on either The supramolecular approach would not be complete without the materials based on hydrogen bonds Among intermolecular interactions, the latter is characterized by its directionality and moderate strength (Table 21) It is very interesting to clarify whether the light-driven mass transport demonstrated for ionic complexes of azobenzene is as well effective in the H-bonded supramolecular materials Recently, a main-chain supramolecular azobenzene polymer based on selfcomplementary quadruple hydrogen bonds has been developed (Fig 24e) (Gao et al, 2007b).

1 -3

It consists of azobenzene-containing building blocks connected by H-bonds forming a main-chain polymer as depicted in Fig 24e The lms prepared by casting exhibited 15-nm deep SRG with grating spacing of 780 nm upon 40-min holographic irradiation using p-polarized beams of moderate intensity of 100 mW/cm2 The authors report that the induced structures are thermally stable up to 1001C Moreover, the mechanism of thermal erasing of the grating has been investigated by in situ temperature-dependent FT IR spectroscopy It has been shown that the amide groups change from Z into E conformation by heating to 1501C, which breaks quadruple hydrogen bonds Such disassembly of supramolecular polymer leads to the disappearance of the surface relief structure As the gratings inscription in the H-bonded main-chain supramolecular polymer was very ineffective, the authors developed an azobenzene-containing supramolecular side-chain polymer, as it is shown in Fig 24f (Gao et al, 2007a).

1 -2

Since the number of connections is drastically reduced by eliminating the need for one or two adapters per blade, there is no need to aggregate connections in a switch module The few NICs and/or HBAs on the Control blade simply connect to external switches, giving the flexibility to use whatever Ethernet or Fibre Channel switches already exist in the environment The backplane, originally designed before InfiniBand had gained traction, is a cell-based ATM fabric from Emulex, InfiniBand-like in terms of latency It operates with a data transfer rate of 25Gbps over redundant point-to-point switched fabric interconnects This is likely to change to 10GbE over time The software that manages the entire virtualized environment is called PAN Manager, and it provides a broad range of functionality Features include the pooling and partitioning of blades within and across BladeFrames, allowing work to be assigned to appropriately sized blades, within a BladeFarm.

Fig. 5.3 Tafel diagrams for the cathodic and the anodic current density for a = 0.25 and y0 = 1(T4 A cm"2 For an anodic process, the quantities a and b are given by the relationships

A 300-nm deep grating was inscribed in this material under similar irradiation conditions Note that at the same time the photoorientation ability of the azobenzene was a few times smaller than in the supramolecular main-chain polymer The induced SRGs are thermally stable up to 1201C A series of.

PAN Manager also provides clustering and failover capability for HA, Disaster Recovery snapshot functions, named processor pools, warm blades (powered up and run in a low power setting, essentially on standby), and the ability to change configurations while running adding HBAs, NICS, storage, and so on..

a

[Irie, 1993]

(5.2.33)

BladeFrames support blades running Red Hat Linux, SUSE Linux, Windows, and Solaris 10. There are also specific solutions for Oracle Grid, 9i and 10g with RAC applications, Microsoft Exchange, and SAP. Since the virtualized I/O architecture requires customized drivers, OS environments may require some level of development from Egenera. As of late 2006, efforts were underway to add support for VMware ESX and Xen virtualization environments. The Egenera architecture is different in its approach to power and cooling as well. The elimination of disks, NICs, and HBAs from the processor blades reduces their individual power and cooling requirements. In general, the reduction in the number of components per chassis reduces the overall power and cooling requirements per BladeFrame. In addition, each blade has power and cooling on the blade, sized to each chipset, which means that there is no need to change power supplies as newer, denser blades are introduced and added into

HEAM [Menzel, 1995]

(5.2.34)

4.4 2.5

(5.2.35)

16

16 (resp. 10a) 2.7 (resp 2.7)

Very often, the value of the formal electrode potential E'o is not known for an irreversible electrode reaction. The overpotential rj cannot, therefore,

an existing BladeFrame. The BladeFrame is cooled front-to-back and can be positioned as close as six inches from the back wall (all components are inserted from the front, with only four power cables out the back). Egenera holds four patents focused on power management, virtualized I/O, and clustering.

262 be determined and the Tafel equation is then used as an operational formula in the form E = a + blog\j\ (5.2.36)

a in 1C per mol% azo in the polymer. NIPA poly(N-isopropylacrylamide), HEAM hydroxyethylacrylamide, HPMC hydroxypropyl methylcellulose. N.A. not available.

It is often useful to replace this equation by Eq. (5.2.24) modified for an irreversible process (occurring at large overpotentials), which has the following form for cathodic processes:

a more polar azobenzene with 4umethoxyethyloxy substituent. not shown in the ref, our estimate uses LCST of c.a. 551C for the unmodi ed chain.