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logK a s s = 1.15, so that at c = 0 . 1 m o l - d m 3 , 32 per cent of the KC1 is present as K + C1~ pairs. In acetic acid ( D = 6.2), log Kass = 6.9, i.e. at the same concentration aass = 99.9 per cent. A remarkable example is the association of 3 x 10~ 5 M tetraisopentylammonium nitrate in pure water and in pure dioxan (D = 2 . 2 ) . While in water the concentration of ion pairs is negligible, the concentration of free nitrate ions in pure dioxan is 8 x 10~ 1 2 mol d m " 3 . Thus, the free ions are practically absent in low permittivity solvents (D < 5). J. Bjerrum (1926) first developed the theory of ion association. H e introduced the concept of a certain critical distance between the cation and the anion at which the electrostatic attractive force is balanced by the mean force corresponding to thermal motion. The energy of the ion is at a minimum at this distance. T h e method of calculation is analogous to that of Debye and Hiickel in the theory of activity coefficients (see Section 1.3.1). The probability Pi dr has to be found for the ith ion species to be present in a volume element in the shape of a spherical shell with thickness dr at a sufficiently small distance r from the central ion (index k). When using the Boltzmann distribution, the relationship for the fraction of ions of the ith kind dNj/Ni in this spatial element is r (1.2.15)

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The observed instability of the light-induced orientation of chromophores is caused by the ionic nature of the azobenzene polyelectrolyte materials Unlike as in the functionalized polymers (Fukuda et al, 2006; Kulikovska et al, 2002), in this case polymer chains provide for a spatial distribution of charges that counteracts the orientation effect of polarized light, returning the ionic chromophores to their initial positions Stable light-induced anisotropy in ionic complexes of poly(vinyl-N-alkylpyridinium) with Methyl Orange has been recently obtained (Zhang et al, 2008; Xiao et al, 2007) Both complexes have chemical structure (see Fig 210a) similar to the complexes reported earlier (Lin et al, 2003, 2002) However, supposedly due to different synthetic procedure, they form smectic A (SmA) liquid crystalline phases Induction of birefringence in one of these complexes is shown in Fig 211..

where z^ip is the potential energy of the ion (i.e. the electrostatic energy necessary for transferring the ion from infinite distance). For small r values, the potential ip can be expressed only in terms of the contribution of the central ion, ip = zke/4jzer, so that the probability density Pt is then given by the equation d ztzke2 * \ ) (1.2.16)

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Orthogonal polarization component Fit to the orthogonal polarization component Intensities of probe beam (V)

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Fig. 1.6 Bjerrum's curves of probability: (1) uncharged particles, (2) two ions with opposite signs (After C. W. Davies)

whose shape is depicted (for ions k and i of opposite sign) in Fig. 1.6. A sharp minimum lies at the critical distance rmin, obtained from Eq. (1.2.16) using the condition d/^/dr = 0:

0.0 Irradiation 0 10 20 30 Time (min) 40 50

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For aqueous solutions at 25 C, rmin = 3.057 x 10"10 ztzk (in metres), i.e. about 0.3 nm, for a uni-univalent electrolyte and about 1.4 nm for a bi-bivalent electrolyte. This distance is considered to be the maximum distance beyond which formation of ion pairs does not occur. Integration of Eq. (1.2.15) permits calculation of the fraction of ions present in the associated state and thus the degree of association and the association constant

Intensity of the transmitted probe beam(a.u.) 1.4 Intensities of probe beam (V) 1.3 1.2 1.1 0.2 0.1 0.0 Irradiation 140 145 Time (min) State 1 State 2 State 1 State 2 State 1 State 2 State 1 (b) 150

where y = 2rmjr and b = 2rmin/a, a being the distance of closest approach of the ions. J. T. Denison and J. B. Ramsey, W. R. Gilkerson and R. M. Fuoss obtained simplified expressions in the form -In ztzke AnkTa e AnkTae

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