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A comparison of the transfer between two species in a vacuum and in the condensed phase reveals marked differences Figure 54A depicts the energy levels of an electron in two species, where level eA in species A is occupied and level eB in species B is empty If these levels had different energies, as indicated in the figure, then the non-radiant energy transfer would be.

When computers decentralized in the 1980s and 1990s, so did their storage With the advent of local area networks, file servers, and decentralization, came both innovation and challenges that arose with the first system crash or disk failure Whose job was it to back up all the newly dispersed storage Initially, individuals were tasked with securing their own data When that failed miserably, there was a movement toward both centralized backup and centralized storage, thereby securing the valuable corporate resource the data Following on the heels of LANs and LAN file servers, specialized storage servers were introduced as NAS appliances These appliances started essentially as special-purpose, stripped-down file servers, which allowed a large amount of data to be stored on the appliance and shared by multiple servers and workstations.

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Borger V, Kulikovska O, G Hubmann K, Stumpe J, Huber M, Menzel H 2005 Novel polymers to study the in uence of the azobenzene content on the photo induced surface relief grating formation Macromol Chem Phys 206:1488 1496 Brown GH, editor, 1971 Photochromism Techniques of Chemistry Vol III New York, London, Sydney, Toronto: Wiley Interscience p 510 Bublitz D, Fleek B, Wenke L 2001 A model for surface relief formation in azobenzene polymers Appl Phys B 72:931 936 Bublitz D, Helgert M, Fleck B, Wenke L, Hvilsted S, Ramanujam PS 2000 Photoinduced deformation of azobenzene polyester lm Appl Phys B 70:863 865 Callari F, Petraia S, Sortino S 2006 Highly photoresponsive monolayer protected gold clusters by self assembly of a cyclodextrin azobenzene derived supramolecular complex Chem Commun 1009 1011 Camilo CS, dos Santos DSJ, Rodrigues JJJ, Vega ML, Campana Filho SP, Oliveira ONJ, Mendonc a CR 2003.

Fig. 5.4 Electron transfer in vacuo and in solution. (A) When the electron donor and the proton acceptor have very different corresponding energy levels the electron transfer is impossible. (B) When the reaction partners are present in a solution, then a change in their configuration can bring their corresponding energy levels close together (dashed line) so that electron transfer is possible. (C) An analogous situation is in the system of an electrode and an electroactive particle in solution

Surface relief gratings and photoinduced birefringence in layer by layer lms of chitosan and an azopolymer Biomacromolecules 4:1583 1588 Chaput F, Lahlil K, Biteau J, Boilot J P, Darracq B, Levy Y, Peretti J, Safarov VI, Lehn J M, Fernandez Acebes A 2000 Design of optical components and optical data storage in photochromic sol gel lms containing dithienylethene or azobenzene derivatives Proc SPIE 3943:32 37 Che Y, Sugihara O, Fujimura H, Okamoto N, Egami C, Kawata Y, Tsuchimori M, Watanabe O 2002 Stable surface relief grating with second order nonlinearity on urethane urea copolymer lm Opt Mater 21:79 82 Chigrinov V, Prudnikova E, Kozenkov V, Kwok H 2002 Synthesis and properties of azo dye aligning layer for liquid crystal cells Liq Cryst 29:1321 1327 Chigrinov V, Muravski A, Kwok HS 2003 Anchoring properties of photoaligned azo dye materials Phys Rev E 68:061702 061705.

NAS appliances proliferated in an effort to decouple storage from individual workstations and centralize storage and storage management, yet maintain a decentralization of computing power Within a few years, in many enterprise data centers large amounts of storage began to be decoupled from computers and attached to networks called storage area networks (SANs) Steady advances in storage and storage network technology continue to contribute to the steady growth of SANs..