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Moreover it gave rise to the fundamental questions about the role of the intermolecular interactions and especially of the polymer matrix for photoinduced orientation and mass transport The effects remained relatively unnoticed as long as the high ef ciency of the processes was attributed to the covalent bonding of azobenzene to polymer chains With demonstration of very effective orientation and mass transport in materials with noncovalent interactions they become very important In this respect, a comparison of a series of supramolecular materials would be quite interesting Further it would be useful to analyze the photoinduced processes in relation to their length scales under consideration of the effects of intermolecular interactions and matrix properties, such as elasticity, free volume, order, and morphology.

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5.3 The Theory of Electron Transfer 5.3.1 The elementary step in electron transfer This part is concerned with discussion of the reaction mechanism in a narrower sense, i.e. the 'microscopic' elementary step in the electrode reaction, connected with the transfer of a single electron between the

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One more problem may be reconsidered in relation to the photoinduced processes in supramolecular materials thermal stability of the induced structures and how is it affected by the ionic interactions First studies demonstrated relatively high thermal stability of induced anisotropy and SRG in both ionic and H-bond material systems The ionic interactions have been suggested to increase the stability Precise explanation of the effect requires further investigations..

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267 electrode and the oxidized or reduced form of the electroactive substance The possibility of adsorption interaction between the electrode and the electroactive substance is excluded The contemporary theory of chemical reactions attempts to describe similar microscopic steps on the basis of construction of the potential energy hypersurface of the reacting system if the applicability of the BornOppenheimer approximation can be assumed In this approximation, also called the adiabatic approximation, the nuclear motion of the atoms (forming the molecules of the reactants and products) is supposedly independent of the motion of the electrons forming the electron shells of these atoms The path of the reacting system across this hypersurface is termed the system trajectory An advantageous system trajectory passing through a minimum in the valley of the energies of the reactants and products and through a saddle point on the hypersurface is the reaction path of the system.

money ran out and the project wasn t completed and tested until 1951 This test demonstrated the first commercial computer to use a magnetic tape storage system It had eight tape drives, each of which was six feet high and three feet wide It used half-inch tape that was 1,200 feet long and recorded data on eight channels at 100 inches per second with a transfer rate of roughly 72KB per second Then in the mid 1950s, IBM developed a radical new magnetic disk storage device they coupled with the RAMAC (random access method of accounting and control) computers called the 350 C disk drive This new disk storage system had an extremely large capacity for the time, rapid access, and low cost It stored 5MB on 50 24-inch disks with a maximum access time of 08 seconds.

The reviewed results show that since the rst demonstration of the photoinduced anisotropy in supramolecular complexes in 2005 and SRGs in 2006 the eld has attracted much attention. The appeared works clearly demonstrated the eligibility of the supramolecular approach for light-induced processes and outlined the possibilities of material design. The achieved values shape very positive prospects for optical application. It can be expected that systematic studies will result in further improvement of the effects. The fundamental questions emerged from this approach are of particular importance not only for supramolecular materials but also for understanding of light-induced orientation and mass transport. The solutions may give new insights into physics of the processes. This combination of both application and fundamental aspects makes the approach so interesting for further investigations.

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