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PANTA s PANTAmatrix blade solutions can hold up to 128 blades per standard rack. Within each chassis or 8U subrack, PANTA supports three types of blades (or as PANTA calls them, modules ): compute modules, visualization modules, and switch modules (see Figure 16.7). Compute modules support two- or four-processor Opteron chips, single- or dual-core, with dual 4x InfiniBand interconnects (20Gbps expandable to 60Gbps), and GbE ports for system management. PANTA uses HyperTransport (80Gbps) to create dynamic SMP between two adjacent computing modules (blades) (up to 16 processors 8 dual-core). Computing modules support both diskless and local disk configurations. Visualization modules support two NVIDIA graphic-processing

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Elimination of E 0 ' from this equation yields Hi = aAHl + (1 - a)AH()c (5.2.55) The third type of activation energy is the activation energy at constant overpotential (rj RT/F), defined by the equation

Figure 2.19. Schematic illustration of the SRG formation in an H-bonded supramolecular liquid crystalline polymer lm and the strategy for the selective detachment of azobenzene unit. Source: Zettsu et al., 2008. Reproduced with permission from Wiley-VCH.

266 Table 5.2 Activation energies of electrode reactions (From R. Tamamushi and from A. A. Vlcek) Electrolyte solution 1 M NH 3 , 1 M NH4C1

In this chapter, the authors have reviewed the very recent results on photoinduction of anisotropy and SRGs in azobenzene-based supramolecular materials. They have tried to discuss these results starting from and in the framework of other materials well known for these phenomena, like low-weight molecular compounds

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System Cu(NH3)22+ + 2e + Cu(Hg) Ei^ + e^Eu" MnO4~ + e + MnO42~ Tl+ + e* Tl(Hg) V ni + e+ V n VIV + e V m Co(NH3)63+ + e * Co(NH3)62+

and doped and functionalized polymers, emphasizing the ne distinctions brought by the supramolecular character of the new materials The new materials are based on H-bond bridges or electrostatic interactions of oppositely charged ionic species.

A/Z^kJ-moP 1 ) 20.9 37.6 19.6 8.0 32.6 59.0 53.0"

boards per blade/module for applications that require high-performance visualization capabilities. Their switch modules, which are in effect switch blades (different form factor than other vendors switch modules), are 24-port 4x InfiniBand switches, which create the I/O subnet(s) across all modules. The switch module can interface to external gateways for GbE, FC, or IB subsystems, in effect virtualizing the I/O into the PANTAMatrix.

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The advantages provided by the application of the basic building block principle of supramolecular chemistry are beyond any doubt: (i) a large variety of ionic and H-bonding azobenzene derivatives are easily accessible; (ii) very high dye concentrations with homogeneous distribution can be obtained; (iii) a large variety of ionic and H-bonding polymer matrixes are known and readily available; (iv) practically any material property can be optimized by combination of appropriate passive polymer and active dye components: exibility in design is of high importance for applications, as the materials may be tuned to match speci c requirements, such as wavelength, combination with anisotropy, reversibility, stability, wetting/dewetting, adhesion; (v) materials can be processed from environment friendly water alcohol solutions, which on the contrary causes their humidity sensitivity; and (vi) owing to their solubility in polar solvents, the materials can be combined with conventional polymers for fabrication of stacked layers.

For an anodic process, this quantity is given by a relationship following from Eqs (5.2.28), (5.2.26), (5.2.53) and (5.2.55): AHl = AHl - (1 - a)nFrj and for a cathodic process by the relationship AHl = AHl + cmFri (5.2.58) Table 5.2 lists examples of the activation energies of electrode reactions. References

But the reviewed research answered the decisive questions about the possibility of the photoinduction of molecular orientation and mass transport and their ef ciencies and stabilities of the induced structures in the new materials Just to highlight the achievements, the remarkably high photoinduced molecular orientation in ISA complexes is noticed here, resulting in the highest dichroic ratio of 1:50 reported up to now The most effective light-induced mass transport was observed in the ionic complexes of azobenzene and polyelectrolyte, where the SRGs as deep as 165 mm were recorded These results are comparable if not superior to the best functionalized polymers They open new perspectives for applications of azobenzene-containing materials Such a high ef ciency of photoinduced processes in supramolecular materials has not been completely explained so far.

PANTA Systems started shipping their first products in the third quarter of 2005. A year later, they had approximately 12 revenue-generating customers and a goal for profitability in the 2008 timeframe. What makes PANTA different is that they perform only the design and development functions, and depend on strategic partners to manufacture and support their offerings. Some of these partners include Tatung, AMD, Mellanox, SilverStorm, Voltaire, and Akivia.

See references on page 253 Delahay, P., Double Layer and Electrode Kinetics, John Wiley & Sons, New York, 1965. Parsons, R., Electrode reaction orders, charge transfer coefficients and rate constants. Extension of definitions and recommendations for publication of parameters. Pure AppL Chem., 52, 233 (1979). Tamamushi, R., Kinetic Parameters of Electrode Reactions of Metallic Compounds, Butterworths, London, 1975. Vlcek, A. A., Relation between electronic structure and polarographic behaviour of inorganic depolarizers. VII. Determination of activation energy of electrode processes. Coll. Czech. Chem. Comm., 24, 3538 (1959).

(5.2.57)

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