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Fig. 3.32a, upon exposure to irradiation with UV light from the downside right and visible light from the upside right simultaneously, the ring rolled intermittently toward the actinic light source, resulting almost in a 3601 roll at room temperature. This is the rst example of this kind of photoinduced motion in a single-layer lm, although the rolling of the LCE ring shown here was slow and stopped when the ring was broken by irradiation. Furthermore, they prepared a plastic belt of the LCE-laminated lm by connecting both ends of the lm, and then placed the belt on a homemade pulley system as illustrated in Fig. 3.32b. By irradiating the belt with UV light from top right and visible light from top left simultaneously, a rotation of the belt was induced to drive the two pulleys in a counterclockwise direction at room temperature as shown in Fig. 3.32c. A plausible mechanism of the rotation is as follows: Upon exposure to UV light, a local contraction force is generated at the irradiated part of the belt near the right

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A HOPG contains well-ordered crystallites, whose angular scatter is typically less than 1 The faces parallel to the plane of carbon hexagons (100), also called basal planes, show chemical and electrochemical properties significantly different from those of the perpendicular (edge) planes (110) The latter contain unsaturated carbon atoms (dangling bonds), which are highly active, for example, against oxidation with oxygen, both chemical and electrochemical The structure of thus formed surface oxides on carbons is very complex, but it can be derived from the common oxygen functional groups known from organic chemistry: carboxyl, hydroxyl, and carbonyl These occur on the oxidized carbon surface either individually or in various combinations: surface anhydride, ether, lactone, etc (see Fig 527) Surface carbonyls (quinones) are reversibly reducible; further anodic oxidation of graphite and carbons occurs through intermediates such as mellithic acid to finally give CO2.

Figure 3.30. (a) Photographs of photoinduced deformation of the polymer lm. (b) Schematic illustration of the effect of the photoinduced change in LC alignment (E: polarization direction of laser beam). Source: Tabiryan et al., 2005.

The basal plane of graphite (or HOPG) is essentially free from surface oxygen functionalities This is manifested by almost flat, featureless.

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pulley along the alignment direction of the azobenzene mesogens, which is parallel to the long axis of the belt. This contraction force acts on the right pulley, leading it to rotate in the counterclockwise direction. At the same time, the irradiation with visible light produces a local expansion force at the irradiated part of the belt near the left pulley, causing a counterclockwise rotation of the left pulley. These contraction and expansion forces produced simultaneously at the different parts along the long axis of the belt give rise to the rotation of the pulleys and the belt with the same direction. The rotation then brings new parts of the belt to be exposed to UV and visible light, which enables the motor system to rotate continuously.

voltammetric curves in aqueous electrolytes, and relatively low charging currents. Unlike platinum, the basal plane HOPG virtually does not adsorb anions and most organic substances. Some molecules, such as phtalocyanines or porphyrines, form, however, n-n complexes with graphite, and are thus strongly adsorbed, being oriented parallel to the basal plane. The most popular carbon material for electrochemistry is probably the glass-like carbon. (This term is preferable to the common names 'glassy carbon' and 'vitreous carbon', which are actually trade marks and should not be used as terms.) Glass-like carbon is prepared by pyrolysis of suitable polymers, e.g. polyfurfurylalcohol or phenolic resins. If the heating programme is properly controlled, the gaseous by-products of pyrolysis evolve sufficiently slowly and the final product is a monolithic, hard carbon, showing very low porosity and permeability to liquids and gases. Glass-like carbon is, in contrast to graphite, isotropic in electrical conductivity and other physico-chemical properties. This explains its structure, characterized by randomly oriented strips (lamellae) of pseudographitic layers of carbon hexagons. The lamellae occasionally approach the graphitic interlayer spacing (335 pm), forming extremely small graphitic regions with crystalline dimensions L a , Lc of the order of 1-10 nm. These regions are interconnected by a non-graphitic carbon material as shown in Fig. 5.28. A similar three-dimensional network of graphitic microcrystallites can also be found in other forms of 'amorphous' carbon, and, according to the forces needed for breaking the network crosslinks (orientation of crystallites), we can classify almost all the solid carbons as hard (nongraphitizable) and soft (graphitizable) ones. Most polycrystalline carbons, including glass-like carbon, show an increase of electrical conductivity with increasing temperature; they can be regarded as intrinsic semiconductors with a band-gap energy of several tens to hundreds meV.

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