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Figure 3.27. (a) Photographs of the ferroelectric LCE lm that exhibits bending and unbending behavior upon alternative irradiation with UV and visible light at room temperature: the lm bent toward the actinic light source along the alignment direction of mesogens in response to irradiation at l = 366 nm, and being attened again by irradiation with visible light at lW540 nm. (b) Change of the load on the ferroelectric LCE lm when exposed to UV light at l = 366 nm with different intensities at 501C. The cross-section area of the lm is 5 mm 20 mm. An external force of 20 mN was loaded initially on the lm to keep the length of the lm unchanged. Source: Yu et al., 2007.

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Metals are the most important electrode materials. Because of the readily renewable surface of mercury electrodes, they have been for several decades and, to a certain degree, still remain the most popular material for theoretical electrochemical research. The large-scale mercury electrode also plays a substantial role in technology (brine electrolysis) but the general tendency to replace it wherever possible is due to the environmental harmfulness of mercury. At mercury electrodes the geometric and actual surface areas are identical. There is no site on the electrode that is energetically preferable to any other site (except for the deposition of heterogeneous patches). Except at rather positive potentials, the mercury electrode is usually not covered with a film of insoluble oxides or other compounds. A liquid gallium electrode has similar properties to the mercury electrode (at temperatures above 29 C), but it has a far greater tendency to form surface oxides. Mercury electrodes require far less maintenance than solid metal electrodes. Especially for the dropping mercury electrode, a noticeable amount of impurities present in the solution at low concentrations (<10~5 mol dm"3) cannot appreciably reach the surface of the electrode through diffusion during the drop-time (see Section 5.7.2). Solid metal electrodes with a crystalline structure are different. The crystal faces forming the surface of these electrodes are not ideal planes but always contain steps (Fig. 5.24). Although equilibrium thermal roughening corresponds to temperatures relatively close to the melting point, steps are a common phenomenon, even at room temperature. A kink {half-crystal position Fig. 5.24c) is formed at the point where one step ends and the

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28 Apr 2007 ... In the following Step-By-Step Guide we'll create a local report ( RDLC file) which features barcoding capabilities by using Barcode Professional ...

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Figure 1.7. An azobenzene dendrimer containing three azo moieties. Each chromophore has two isomerization states (trans and cis), leading to four distinct photoisomers for the dendrimer molecule. All four isomers have different physical properties.

Fig. 5.24 Crystalline metal face: (a) ad-atom, (b) ad-atom cluster, (c) a kink (half-crystal position), (d) atom at the step, (e) atom in the kink, (f) vacancy, (g) vacancy cluster. (According to E. Budevski)

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Rubner, 2000) (in the case of weak polyelectrolytes) of the assembly solution, the polyelectrolyte chain conformation is modi ed, and hence the resulting lm architecture is tuned. For instance, one can control thickness (Losche et al., 1998; Dubas and Schlenoff, 1999), permeability (Rmaile and Schlenoff, 2003), morphology (Antipov et al., 2003; McAloney et al., 2003; Mendelsohn et al., 2000), and density (Dragan et al., 2003). Recently the technique has been modi ed to assemble the alternate layers using a spin-coater, which reduces the assembly times and adsorption solution volumes considerably (Chiarelli et al., 2001; Cho et al., 2001; Lee et al., 2003, 2001). As a lm preparation technique, this method has numerous advantages. The adsorption of the polymers is quasithermodynamic, with the chains adsorbing into a local minimum, which makes the lms stable against many defects (dewetting, pinhole formation, etc.). Importantly, the technique is not limited to at surfaces: any geometry that can be immersed in solution (or have solution owed through)

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