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smectic C* phase (Negishi et al., 1996a). In this system, the chiral dopant also acts as a photoresponsive molecule; therefore, a change in molecular shape of the dopant is expected to affect signi cantly the phase structure of the smectic C* phase because the molecular shape of the dopant is crucial for the induction of the smectic C* phase. The azobenzene with a cyclic carbonate is quite effective at inducing the photochemical ip of polarization of the ferroelectric LC mixture (Negishi et al., 1996a). Furthermore, azobenzene derivatives that exhibit antiferroelectric properties were developed, and their photoresponsive behavior was

One of the biggest issues in their deployment was in power and cooling. Because of the size and importance of this project, they had the luxury of starting fresh and engineering the data center for high-density computing. Upgrades included additional Power Distribution Units (PDU), (providing ~25kW power per rack of blade servers (65KBTU) per rack), additional chillers (they had a supercomputer in there previously, so water cooling was already in place), hot/cool zones to support optimal airflow for heat dissipation (120 tons of additional cooling), and vented floor tiles that funnel cooling in front of

I,III(s) I(s), IJI(s) UI(s) I,H(s) I,III(s) I,III(s) I,HI(s) IJII(s) I,III(s) I,III(s)

O

I,III(s)

each rack from the chillers. In total, their implementation requirements were as follows:

Source:

I indicates the Volmer mechanism (Eq. 5.7.1), II the Tafel mechanism (Eq. 5.7.2) and III the Heyrovsky mechanism (Eq. 5.7.3). The slowest step of the overall process is denoted (s).

transmission coefficient, * exp - ^r2) (5.7.4)

Egenera 20kW/frame, up to 24 blades per frame, 4-socket, dualcore processors = 192 cores per frame/rack. IBM 24kW/rack (6-chassis configuration); they use mostly 5-chassis/rack, 14 blades/chassis, 2-socket, dual-core = 280 cores/rack, partially populated Egenera 65K BTU/frame IBM 68K BTU/rack (6-chassis configuration)

examined (14a, b) (Negishi et al., 1996b). The photochemical ip of polarization in these antiferroelectric LCs is induced very effectively (Negishi et al., 1996b), and a device fabricated with these antiferroelectric LCs was explored (Shirota and Yamaguchi, 1997).

where m is the mass of the proton or its isotope, h is Planck's constant, (ox is the vibrational frequency of the bond between the proton and the rest of the molecule of the proton donor, cof is the vibrational frequency of the bond between the hydrogen atom and the metal and r is the proton tunnelling distance. When the hydrogen atom is weakly adsorbed, the vibrational frequency of the hydrogen-metal bond w{ is small and the proton tunnelling

3.4.4.3. Photochemical Phase Transition of Azobenzene LC Polymers. LC polymers possess properties of both polymers and LCs and currently are regarded as promising photonic materials because of their advantageous properties mentioned earlier. Wendorff and coworkers reported the rst example of a photon-mode photoresponse in LC polymers, namely, holographic recording in LC polymer lms containing azobenzene moieties and mesogenic groups (Eich et al., 1987; Eich and Wendorff, 1987). Ikeda et al. (1990a,b, 1988) reported the rst example of the photochemical phase transition in LC polymers; they demonstrated that by irradiation of LC polymers doped with LMW azobenzene derivatives with UV light to cause trans cis isomerization led to a nematic isotropic phase transition; upon cis trans back-isomerization, the LC polymers reverted to the initial nematic phase. Although doping the chromophores in a matrix is most convenient, the resultant LC polymer systems often exhibit instabilities, such as phase separation and microcrystallization. This occurs because of the mobility of the azobenzene chromophores in the matrix and the propensity of the dipolar azobenzene units to form aggregates. Higher quality LC polymer systems are obtained when the azobenzene moiety is covalently bound to the host polymer matrix, and this approach is now preferable for most applications. These materials combine the stability and processability of LC polymers, with the unusual photoresponsive behavior of the azobenzene groups. A variety of

The lesson to be learned here is that if the room is properly designed, implemented, and managed, the density of blades is not a problem However, this involves planning and proper room-level power and cooling Most blade vendors offer professional services to evaluate power and cooling issues and make recommendations But according to the organization, It s worth it Tools are also available to help with ongoing monitoring, such as IBM PowerExecutive and PAN Manager s temperature monitoring Invest early in resolving potential cooling issues Other challenges arose around the complexities of the Egenera virtualization layer, particularly with respect to troubleshooting: When everything is working, there is no problem, but when something goes wrong, that extra layer makes it difficult to troubleshoot But it s worth it due to the failover and high performance we get with Egenera Another important lesson test all applications thoroughly before deploying them.