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azobenzenes, for example, has a rodlike shape, which stabilizes the phase structure of the LC phase, whereas its cis isomer is bent and tends to destabilize the phase structure of the mixture. As a result, the LC isotropic phase transition temperature (Tc) of the mixture with the cis form (Tcc) is much lower than that with the trans form (Tct) (Fig. 3.18). If the temperature of the sample (T) is set at a temperature between Tct and Tcc, and the sample is irradiated to cause trans cis photoisomerization of the azobenzene guest molecules, Tc decreases with an accumulation of the cis form. When Tc becomes lower than the irradiation temperature T, an LC isotropic phase transition of the sample is induced. Photochromic reactions are usually reversible, so the sample reverts to the initial LC phase through cis trans back-isomerization. Thus, phase transitions of LC systems can be induced isothermally and reversibly by photochemical reactions of photoresponsive guest molecules (Fig. 3.18). 3.4.4.2. Photochemical Flip of Polarization and Alignment Change in Ferroelectric LCs. Photochromic reactions can also strongly in uence the phase structures of various LCs. Ferroelectric LCs exhibit spontaneous vb.net code 128 Packages matching Tags:"Code-128" - NuGet Gallery
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