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temperature. With the progress of polymerization, the polymer main chains that formed prevented close packing of mesogens, which resulted in a decrease in birefringence when the alignment of mesogens before polymerization was high; in contrast, the polymer chains enhanced the packing of mesogens when the alignment of mesogens before polymerization was low. Serrano and coworkers studied the photopolymerization of mixtures of mono- and difunctional LC monomers to yield polymer materials with different degrees of cross-linking (Sanchez et al., 1999). Oriented lms can be prepared by controlling the alignment of the monomers. The birefringence of photopolymerizable samples and polymer lms, as well as its temperature dependence, was evaluated. The birefringence of the lms increased as the content of the monofunctional LC monomer increased. Furthermore, LCEs have been prepared by block copolymerization and hydrogen bonds (Cui et al., 2004; Li et al., 2004). Li et al. (2004) proposed a musclelike material with a lamellar structure based on a nematic triblock copolymer (Components 8a c, Fig. 3.10). The material consists of a repeated series of nematic (N) polymer blocks and conventional rubber (R) blocks. The synthesis of block copolymers with well-de ned structures and narrow molecular-weight distributions is a crucial step in the production of arti cial muscle based on triblock elastomers. Talroze and coworkers studied the structure and the alignment behavior of LC networks stabilized by hydrogen bonds under mechanical stress (Shandryuk et al., 2003). They synthesized poly[4-(6-acryloyloxyhexyloxy)benzoic acid], which

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Fig. 5.13 Steady-state voltammograms: (1) reversible voltammogram (Eq. 5.4.24); (2) quasireversible voltammogram (Eq. 5.4.22) for /c = 10~4cm s"1; (3) irreversible voltammogram 5 1 (Eq. 5.4.26) for = l(T cm s" . E '' = -0AV, a = 0.3,

= 2 x 10~4 cm s"1, ; d = 10~4 A cm"

Figure 3.10. Chemical structures of a side-on nematic monomer (8a) and a striated arti cial muscle with a lamellar structure based on a nematic triblock copolymer, RNR (N: nematic; R: rubber). Source: Li et al., 2004.

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OpSource, founded in 2002 as a web hosting company, began the shift to Software as a Service (SaaS) in 2004. OpSource differentiates themselves from other application management and hosting providers by offering complete service delivery priced on demand, including managed services, call-center support provided under the software company s brand, and application management. Their business is based on their patent-pending OptiTech Services Engine, which supports rapid integration and deployment of SaaS offerings.

containing the anodic limiting current. This curve corresponds to the case that equilibrium is established at the surface of the electrode between the reduced and oxidized forms according to the Nernst equation. The dependence of the current density on the potential is not a function of k ~. The reversible polarization curve has the form of a wave (see Fig. 5.13, curve 1). The half-wave potential is given as Em = E nF In

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O O O O O O O H O O H O O O O O O O O O O H O O H O O O H O O H O O O O O O O O H O O H O O O O O O O H O O H O O O O O O O H O O H O

(5.4.25)

As a key part of their transition to SaaS, OpSource felt it was critical to have a uniform platform from which they could deliver their services, with the least amount of time possible to provision new customers and new services. Using their previous platforms of rack-mounted servers, it was taking them 30 days to provision a new customer, with most of that time taken up by racking and stacking the necessary hardware and software. Their key driver was to reduce the time to provision (which has now been reduced to 10 days). Additional drivers were to increase manageability and flexibility in managing their server farms, including managing their Service Level Agreements (SLAs). With their entire business reliant on their server hardware, they needed ways to improve physical server maintenance, with minimal disruption to their customers. They were also looking to improve the efficiency of their hardware, including increasing their server utilization and growing their ability to serve customers while managing their power consumption requirements.

Figure 3.11. Plausible structure of polymer network based on H-bonded rodlike dimers formed by carboxyl monomer units incorporated in the polymer side chains.

This value is close to the formal electrode potential and independent of the convection velocity. The plot of log (;d j)/j versus E is linear with the slope nF/2.303RT. 3. Irreversible polarization curve (voltammogram). If the value of k^ is so small that the first term on the right-hand side of Eq. (5.4.22) is much smaller than the second term, even when / approaches ; d , then the equation assumes the form

exhibits a smectic LC phase over a broad temperature range. Addition of up to 10 mol% of any LMW benzoic acid and, as a result, the formation of mixed dimers do not in uence the smectic CA structure (Fig. 3.11). The amorphous azopyridine polymer can easily be converted into LC polymers through hydrogen bonding with a series of commercially available aliphatic and aromatic carboxylic acids (Cui and Zhao, 2004). The pure acids have only a crystal phase that melts at high temperatures; after mixing them with the azopyridine polymer, the complex that formed showed a new LC phase. This observation is strong evidence for the formation of hydrogen-bonded complexes, because neither the pure acids nor the azopyridine polymer shows any LC phase.

They began looking at blades as a solution in early 2004 and went into production in late 2004. They evaluated virtualization during 2005 and went into production in late 2005.

(5.4.26)

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