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LCEs are usually lightly cross-linked networks. The cross-linking density is known to have a great in uence on the macroscopic properties and the phase structures (Kupfer et al., 1994; Finkelmann and Rehage, 1984). The mobility of chain segments is decreased with an increase in the cross-linking points, and consequently the mobility of mesogens in the vicinity of a cross-link is suppressed. A cross-link is recognized as a defect in the LC structure, and an increase in the cross-linking density produces an increasing number of defects. Therefore, LC polymers with a high cross-linking density are referred to as LC thermosetting polymers (duromers), which are distinguished from LCEs.

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= -nF/cRed[(cRed)JC=0 ~ cLd]

where <5Ox and <5Red are the thicknesses of the Nernst layer for the reduced and oxidized forms and KOX and ic Red are the mass transfer coefficients. Again, the case c Red = 0 will be considered. The limiting cathodic current

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The concept of LCEs was rst proposed by de Gennes (1975), and the rst example of an LCE was prepared by Finkelmann et al (1981) Since then, a variety of LCEs with various structures of main chains and various kinds of mesogens have been prepared Generally, there are two methods of preparation of LCEs: one is the two-step method (Kupfer and Finkelmann, 1994; Zentel and Benalia, 1987; Zentel and Reckert, 1986), and the other is the one-step method (Broer et al, 1988) In the former method, well-de ned weak networks are synthesized in the rst step These networks are then deformed with a constant load to induce network anisotropy In the second reaction step, cross-linking reactions x the network anisotropy.

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The basis for PolyServe s solutions is a share-everything data model. If every blade already has access to all the data, failover or movement of applications or guest OSs from one server to another becomes much simpler. With their Matrix Server software, PolyServe creates shared data clusters, much like what was available with VAXclusters, but for Windows and Linux. PolyServe uses block-mode access to the data via a SAN, enabling high-performance I/O as well as direct I/O capabilities for databases. The bulk of PolyServe s business comes from their Database Utility. The Database Utility supports dynamic rehosting of database instances from one server to another, including high availability for database instances. This capability allows users to easily match workloads with appropriate systems. It also supports multiple database instances on a single system to improve system utilization. PolyServe s Virtual Server Utility is an add-on to Microsoft s Virtual Server. Much like the Database Utility, the Virtual Server Utility supports multiple virtual machine instances and provides support for movement of virtual machines between servers (blades) for workload balancing or for high-availability failover.

Fig. 5.12 Steady-state concentration distribution of the oxidized and of the reduced form of an oxidation-reduction system in the neighbourhood of the electrode

The advantage of this method is that the induced network anisotropy in the rst step is reproducible, so that well-aligned elastomers are obtained (Kupfer and Finkelmann, 1994; Zentel and Benalia, 1987; Zentel and Reckert, 1986) Uniformly aligned mesogenic monomers with two reactive groups or prepolymers with reactive groups can be photochemically or thermally polymerized or cross-linked by nonmesogenic cross-linking agents to give macroscopically aligned LCEs and anisotropic LC networks with different cross-linking densities, in which the macroscopic orientation of the LC states in the solid samples is xed (Fig 39; Kupfer and Finkelmann, 1991) Broer et al (1988) developed the one-step method to prepare highly oriented LC side-chain polymers, namely, the in situ photopolymerization of macroscopically aligned LC monomers Highly ordered polymers may be obtained by polymerizing ordered LC monomers LCEs with various LC phases, such as nematic (Tammer et al.

density is jd=-nFKOxc Ox (5.4.20)

16

, 2005; Kundler and Finkelmann, 1998), cholesteric (He et al, 2005; Meng et al, 2005; Finkelmann et al, 2001), smectic (Beyer and Zentel, 2005; Hiraoka et al, 2005; Zanna et al, 2002; Lehmann et al, 2001; Brodowsky et al, 1999; Nishikawa and Finkelmann, 1999; Gebhard and Zentel, 1998; Nishikawa and Finkelmann, 1997; Brehmer and Zentel, 1994) , and discotic (Disch et al, 1995) were prepared by polymerization of various LC monomers containing more than one polymerizable group For example, a cholesteric LCE (Components 7a d) with a spontaneous and uniform alignment in the form of a helical structure was synthesized (Finkelmann et al, 2001) Dye-doped cholesteric LCEs can act as mirrorless lasers, in which the wavelength of the laser emission can be tuned by external mechanical deformation..

[ ^ < f f ^ ] } (..1 542 )

Figure 3.9. Preparation of LCEs by the two-step method. Source: Kupfer and Finkelmann, 1994.

PolyServe s third solution is the File Serving Utility, which can be used to scale out file services on the fly. Need more storage Simply drag and drop resources into the file server pool to add them to the shared file system nondisruptively.

giving, after substitution for (cOx);t=0 and (c Red ) A . =o from Eqs (5.4.18) and (5.4.19) and rearrangement,

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