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Photoinduced reversible changes in elasticity of semi-interpenetrating network lms bearing azobenzene moieties (Components 6a,b) were achieved by irradiation with UV and visible light (Kim et al., 2005a). The network lms were prepared by cationic copolymerization of azobenzene-containing vinyl ethers in a linear polycarbonate matrix. The network lm showed reversible deformation by switching the UV light on and off. The photomechanical effect is attributed to a reversible change between the highly aggregated and dissociated state of the azobenzene groups (Fig. 3.8) (Kim et al., 2005a,b,c).

Fig. 5.11 Chronopotentiometric curves for a reversible electrode reaction (Eq. 5.4.16) in E-t (upper curve) and E-tV2 (lower curve) coordinates. T denotes the transition time

Clustering solutions and blades, due to their close proximity and shared resources, are complementary to one another. VCS is an excellent example of this, with their N+1 high-availability clustering solution. VCS is a traditional failover product that will work with blades out of the box, just like any other server. Symantec has also partnered with VMware to provide virtual failover capabilities with the ESX virtualization solution. If there is a hardware failure, VCS will fail over the ESX hypervisor, along with the entire virtual environment, to another server (blade).

284 5.4.2 Analysis of polarization curves (voltammograms) Electrode processes are often studied under steady-state conditions, for example at a rotating disk electrode or at a ultramicroelectrode. Polarography with dropping electrode where average currents during the droptime are often measured shows similar features as steady-state methods. The distribution of the concentrations of the oxidized and reduced forms at the surface of the electrode under steady-state conditions is shown in Fig. 5.12. For the current density we have (cf. Eq. (2.7.13))

Poly (6a-random-6b)

nFKOx[(cOx)x==()

1.0 10 2 N

Symantec has created the Veritas Application Director (VAD) to define and manage what resources an application has, then match system resources with the application as well as provide workload balancing across the resources. Over the next few years, expect Symantec to be a big player in this market.

cO)

Azobenzene-containing gels and polymer lms are especially used for applications; however, in general the gels reported have a disadvantage in that the response is slow and the degree of deformation of the polymer lms is too small to be practically used. It is generally agreed now that it is crucial to develop only photomechanical systems that can undergo fast and large deformations. The main challenge in the development of such polymer systems is the conversion of photoinduced effects in some light-reversible functional groups or llers into a signi cant macroscopic deformation of the host materials. The gels and polymer lms used in the studies described earlier were amorphous, without microscopic or macroscopic order, and thus their deformations are isotropic. If materials with anisotropic physical properties are used, the mechanical power produced could increase signi cantly, and more control can be realized.

- c Ox] (5.4.18)

Symantec/Veritas has a wide range of solutions that are applicable to the blade environment, spanning server, security, and storage management. VCS and VAD are excellent examples of solutions that are particularly complementary. As the blade and virtualization spaces grow, expect to see more solutions from Symantec driving a utility computing model.

For a long time it has been known that anisotropic molecules, the so-called mesogenic groups, can form LC phases. The LC phases are thermodynamically stable phases that exist in a temperature range between the crystalline phase and the isotropic melt. The remarkable properties of LC phases stem from their combination of long-range order of crystals with mobility of uids, such as birefringence, uidity, and alignment change by external elds. LC polymers are well-known polymer materials that combine the self-organization of the mesogenic groups into the ordered structure of LC phases with some typical polymer properties. For example, above the glass transition temperature (Tg), these polymers are in the LC state and can be ordered by electric or magnetic elds. Cooling down below Tg, the system vitri es yielding anisotropic glasses. This makes the material suitable for optical applications and for storage devices. LCEs are unique because of the combination of the anisotropic aspects of the LC phases and the rubber elasticity of polymer networks. Because of the LC properties, mesogens in LCEs show alignment, and the alignment of mesogens can be coupled with polymer network structures. This coupling gives rise to many characteristic properties of LCEs. There are a number of excellent books and review articles on the chemistry, physics, and theory of LCEs (Xie and Zhang, 2005; Warner and Terentjev, 2003; Terentjev, 1999; Brand, 1998; Cotton and Hardouin, 1997; Warner and Terentjev, 1996; Kelly, 1995; Zentel, 1989). LCEs have been a hot topic recently because large deformations of LCE materials can be induced by changing the alignment of mesogens in LCEs by external stimuli such as electric elds, changes in temperature, and light. These characteristics make LCEs extremely useful as raw materials for arti cial muscles and soft actuators.

= -nFZ)Red6Red[(cRed)JC=0 - cRed] (5.4.19)