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distributed in an LC phase, trans-cis isomerization can destabilize the phase by lowering the nematic-to-isotropic phase transition temperature (Eich and Wendorff, 1990) This enables fast isothermal photocontrol of phase transitions (Kato et al, 1996; Hayashi et al, 1995; Ikeda and Tsutsumi, 1995; Ikeda et al, 1990) Since these modulations are photoinitiated, it is straightforward to create patterns (Shannon et al, 1994) These LC photoswitching effects are obviously attractive in many applications, such as for display devices, optical memories (Gibbons et al, 1991), electro-optics (Luk and Abbott, 2003), and modulating the polarization of ferroelectric liquid crystals (Fischer et al, 1997; Ikeda et al, 1993) 1133 Dendrimers Dendrimers have been investigated as unique structures to exploit and harness azobenzene s photochemistry (Momotake and Arai, 2004a,b; Villavicencio and McGrath, 2002).

Virtual Iron has some very strong partnerships that have helped them get to this point and will continue to help move them forward. Intel is one of their investors, and they gained early access to Intel s Virtual Technology chip, helping them take advantage of the hardware assist within their solutions. They also have partnered with AMD to support their hardware-assist capabilities. The flip side of this is that Virtual Iron will not run on earlier blades that did not have virtualization hardware assist.

281 component, equals c , then the equations of the limiting diffusion current density yd are obtained for various types of diffusion and convective diffusion; these equations follow from Eqs (2.5.8), (2.7.12) and (2.7.17) after multiplication of the right-hand sides by nF. In the general case, the initial concentration of the oxidized component equals Cox ar*d that of the reduced component c Red . If the appropriate differential equations are used for transport of the two electroactive forms (see Eqs 2.5.3 and 2.7.16) with the corresponding diffusion coefficients, then the relationship between the concentrations of the oxidized and reduced forms at the surface of the electrode (for linear diffusion and simplified convective diffusion to a growing sphere) is given in the form (5.4.6) For the sake of simplicity, it will further be assumed that c Red = 0. For the boundary conditions (5.4.5), i.e. the prescribed ratio of the concentrations of the two forms, we may use the transformation -A(D Ox /D Red ) 1/2 cg 1 + A(DOx/DRed)l/2 Together with the boundary condition (5.4.5) and relationship (5.4.6), this yields the partial differential equation (2.5.3) for linear diffusion and Eq. (2.7.16) for convective diffusion to a growing sphere, where D = DOx and c = CoJ[l +k(DOx/DRed)1/2]. As for linear diffusion, the limiting diffusion current density is given by the Cottrell equation

Dendritic and branched molecular architectures can have better solubility properties and can be used to control undesired aggregation, resulting in higher quality lms for optical applications (Campbell et al, 2006; Ma et al, 2002) Dendrimers with strongly absorbing pendants can act as antenna, harvesting light and making it available, via intramolecular energy transfer, to the dendrimer core In dendrimers with azo cores, this allows for the activation of isomerization using a wavelength outside of the azo-absorption band (since the dendrimer arms absorb and transfer energy to the core) (Aida et al, 1998; Jiang and Aida, 1997) Furthermore, the con gurational change that results from the core isomerization will translate into a larger scale geometric change For instance, in a dendrimer with three azobenzene arms (Fig 1.

jd=-nFclx(^}

Virtual Iron came early to the server virtualization market and, like many, got caught up in the race to work around the x86 s inability to be virtualized. Once

(5.4.8)

7), the various isomerization combinations (EEE, EEZ, EZZ, and ZZZ) could all be separated by thin-layer chromatography because of their different physical properties (Junge and McGrath, 1999) The conformational change associated with isomerization modi es (typically reduces) the hydrodynamic volume, with the speci c extent of conformational change depending strongly on where the azo units are incorporated (Li and McGrath, 2000) 1134 Polyelectrolyte Multilayers A new facile and versatile lm preparation technique, layer-by-layer electrostatic self-assembly, has become the subject of intensive research since its introduction by Decher (Decher, 1997; Decher and Schmitt, 1992; Decher and Hong, 1991; Decher et al, 1991) In this technique, a charged or hydrophilic substrate is immersed in a solution of charged polymers (polyelectrolytes), which adsorb irreversibly onto the substrate.

and, for convective diffusion to a growing sphere (cf. Eq. (2.7.17)), by the Ilkovic equation of instantaneous current, jd = -nFc0Ox(7DoJ3jtt)1/2 (5.4.9)

Intel remedied that situation, Virtual Iron decided to shift over to the Xen 3.0 hypervisor as the basis of their virtualization stack, believing that Xen 3.0 would become a de facto industry standard. VI was then able to leverage 70 80% of the management software from their initial products to deliver solutions quickly to market. This ability to move quickly to get a piece of this growing market and continue to build more capabilities into their management layers will serve them and their customers well.