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The Xen community was originally created by the founders of XenSource to develop a virtualization hypervisor that would become ubiquitous across all markets. The Xen project includes such vendors as AMD, Intel, Cisco, Dell, Egenera, HP, IBM, Mellanox, NetApp, Novell, Red Hat, Sun, Symantec/Veritas, Voltaire, and XenSource, with new vendors becoming involved daily. One of the primary goals of Xen is to provide a common feature set for the nextgeneration virtualization architecture, with near bare-metal performance. Xen continues to lead the paravirtualization hypervisor effort, and is achieving great success via partnerships with Microsoft, Novell, and Red Hat. SUSE Linux Enterprise 10, Red Hat Enterprise Linux, OpenSolaris, and Solaris 10 are shipping or will soon ship with Xen integrated. XenSource s strategic partnership with Microsoft will allow Xen-enabled Linux guests to run paravirtualized under the Windows Hypervisor (Viridian) just as it does under Xen. (Viridian and Xen are both paravirtualizing hypervisors.) A Xen-enabled Linux guest will use native Xen hypercalls to access virtualization functions, and a small adapter will translate the Xen hypercalls into Viridian hypercalls. With both AMD-V and Intel VT chips offering hardware virtualization assist, guest operating systems now can run unmodified on Xen, as well. The Xen 3.0 hypervisor is quickly becoming the basis for nearly all hypervisor implementations.

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Figure 3.2. Synthesis route of poly(amide acid) gels containing azobenzene groups in their backbones and cross-linked with TAPB. Source: Hosono et al., 2007.

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Thermodynamics describes the behaviour of systems in terms of quantities and functions of state, but cannot express these quantities in terms of model concepts and assumptions on the structure of the system, intermolecular forces, etc. This is also true of the activity coefficients; thermodynamics defines these quantities and gives their dependence on the temperature, pressure and composition, but cannot interpret them from the point of view of intermolecular interactions. Every theoretical expression of the activity coefficients as a function of the composition of the solution is necessarily based on extrathermodynamic, mainly statistical concepts. This approach makes it possible to elaborate quantitatively the theory of individual activity coefficients. Their values are of paramount importance, for example, for operational definition of the pH and its potentiometric determination (Section 3.3.2), for potentiometric measurement with ionselective electrodes (Section 6.3), in general for all the systems where liquid junctions appear (Section 2.5.3), etc. The expression for the chemical potential of a component of a real solution can be separated into two terms: & -tf= AjU, = RT \nxi + RT In y,= A^, i d +A M f (1.3.1)

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where Afiild = RT\nXi is the difference in the chemical potentials between the standard and actual states, for ideal behaviour, and Apf is the correction for the real behaviour, which can be identified with the expression containing the activity coefficient. It can further be written for all

Seki and coworkers (2007) developed a new type of photoresponsive polymer gel by introducing an azobenzene moiety on the mobile cyclodextrin part as the sliding cross-linking unit. The synthesis scheme of the gel is shown in Fig. 3.3. The polyrotaxane (PR) was composed of a noncovalent complex between poly(ethylene oxide) and a-cyclodextrin (a-CD, lling ratio: 28% of full complexation) capped with an adamantanamine unit at each end. Onto the sliding ring of CD, three types of azobenzene derivatives (6Az10-, 6Az(EO)3-, and CNAz(EO)3-) were linked by esteri cation. Gelation reactions, namely, formation of gure-of-eight sliding cross-linkages of the azobenzene-linked PR, were performed with 1,1carbonyl diimidazole in dimethyl-sulfoxide (DMSO). Figure 3.4 indicates volume changes of the gels in DMSO upon irradiation of alternate UV and visible light. For all three systems, irradiation of UV light induced expansion of the gels, and visible light the reverse. The change in D/D0 for 6Az10-PR gel reached 25%, which corresponds to a volume change of 80% 100%. It is inferred that such an effective molecule-to-material transformation can be ascribed to the dynamic nature of the cross-linkers (Sakai et al., 2007).

A hypervisor is only part of the virtualization story. The higher-level management capabilities are the more interesting part. XenSource has developed XenEnterprise to be the complementary management interface for Xen. XenEnterprise helps customers install and configure the Xen hypervisor, what XenSource calls 10 minutes to Xen. It also helps customers move their applications from a purely physical server environment to a virtual environment (P2V), as well as perform other management tasks such as VM provisioning/reprovisioning and guest OS configuration/reconfiguration and scheduling. LiveMigrate provides the ability to move a running virtual machine from one system to another. All management is done in compliance with the DMTF CIM standards for visibility to other management platforms, such as HP OpenView or Microsoft Operations Manager (MOM).

(5.4.1) =nFDKed[ \

CH3(CH2)5

(5.4.2)

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6Az(EO)3

In general, for a larger number of electroactive substances, the partial current densities corresponding to the individual substances are additive. It is necessary to clarify the meaning of the distance, x = 0, from the electrode. We must remember that the concentration changes resulting from transport processes appear up to distances considerably larger than the dimensions of the electrical double layer (the space charge region, i.e. the region of the diffuse electrical layer, is mostly spread out to a distance of at most several tens of nanometres). Thus 'zero' distance from the electrode corresponds to points lying just outside the diffuse electrical layer. At this distance, the concentrations of the electroactive substances are not yet affected by the space charge. The influence of the surface charge is shown, however, in the rate constants of the electrode reactions which appear in the boundary conditions (see Section 5.3.2). The current density corresponding to the electrode reaction (5.2.1) is described by Eq. (5.2.13). Combination of Eqs (5.2.13) and (5.4.2) yields

CNAz(EO)3

16

(5.4.3)

(5.4.4)

Figure 3.3. Synthesis scheme of azobenzene-containing slide-ring gels. Source: Sakai et al., 2007.

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