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where n is the coordination number of the cation A + . The energy AG is proportional to the combination of the reciprocal values of the distances between the centres of the corresponding pairs of ions (i.e. the sum of the radii of these ions): (1.2.21) Clearly, it is the size of ions that is decisive in ion-pair formation. Moreover, the coulombic interactions can extend even to more distant neighbours. The Blander equation is then, of course, no longer applicable. References
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During the deswelling, irradiation of the gels with UV light was found to increase the expulsion of water from the swollen gels and decrease the water content of the gels by as much as 20% 30% They suggested that trans cis isomerization of the cross-links causes a local stress eld and lower entropy of the network, which in turn leads to an increase in unfavorable interaction of the network with the solvent, contributing to the increased expulsion of water from the gels Furthermore, an increase in the cross-link density was found to reduce the magnitude of this change (Mun-Sik and Vinay, 2002) Recently, semirigid poly(amide acid) gels containing azobenzene groups in the backbone structure were synthesized with a symmetric trifunctional cross-linker, 1,3,5-tris(4-aminophenyl) benzene (TAPB) (Fig 32).
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Ben-Nairn, A., Hydrophobic Interactions, Plenum Press, New York, 1980. Bloom, H., and J. O'M. Bockris, Molten electrolytes, MAE, 2, 262 (1959). Burger, K., Solvation, Ionic and Complex Formation Reactions in Non-aqueous Solvents, Elsevier, Amsterdam, 1983. Case, B., Ion solvation, 2 of Reactions of Molecules at Electrodes (Ed. N. S. Hush), Wiley-Interscience, London, 1971. Conway, B. E., Ionic Hydration in Chemistry and Biophysics, Elsevier, Amsterdam, 1981. Davies, C. W., Ion Association, Butterworths, London, 1962. Debye, P., Polar Molecules, Dover Publication Co., New York, 1945. Denison, J. T., and J. B. Ramsey, /. Am. Chem. Soc, 11, 2615 (1955). Desnoyers, J. E., and C. Jolicoeur, Ionic solvation, CTE, 5, Chap. 1 (1982). Dogonadze, R. R., E. Kalman, A. A. Kornyshev, and J. Ulstrup (Eds), The Chemical Physics of Solvation, Elsevier, Amsterdam, 1985. Eisenberg, D., and W. Kautzmann, The Structure and Properties of Water, Oxford University Press, Oxford, 1969.
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XenSource, founded in early 2005, has a dual role as a leader in the Xen open source community as the distributor of the Xen (free) hypervisor, and as a software vendor developing and selling value-add virtualization management solutions around the Xen technology. Through both efforts, XenSource evangelizes the benefits of virtualization across all markets. Xen also pioneered the paravirtualization approach to server virtualization, offering significant performance improvements for guest OS environments where the source could be modified to use the paravirtualization API.
Irradiation of laser light with the wavelength of 405 nm induced a local volume change in the gels owing to the deformation of the network structure, and the volume change was reversible by irradiation with visible light or heat The viscoelastic properties of the gels before and after light irradiation were also investigated, and a twofold increase in the storage modulus of the gels was observed upon irradiation of 405-nm laser light (Hosono et al, 2007)..
28 Fuoss, R. M., and F. Accascina, Electrolytic Conductance, Intersceince Publishers, New York, 1959. Gilkerson, W. R., /. Chem. Phys., 25, 1199 (1956). Inmann, D., and D. G. Lovering (Eds), Ionic Liquids, Plenum Press, New York, 1981. Klotz, I. M., Structure of water, in Membranes and Ion Transport (Ed. E. E. Bittar), Vol. I, John Wiley & Sons, New York, 1970. Mamantov, G. (Ed.), Characterization of Non-aqueous Solvents, Plenum Press, New York, 1978. Marcus, Y., Ion Solvation, John Wiley & Sons, Chichester, 1986. Papatheodorou, G. W., Structure and thermodynamics of molten salts, CTE, 5, Chap. 5 (1982). Samoilov, O. Ya., Structure of Aqueous Electrolyte Solutions and Hydration of Ions, Consultants Bureau, New York, 1965. Skarda, V., J. Rais, and M. Kyrs, /. Nucl. Inorg. Chem., 41, 1443 (1979). Sundheim, G., Fused Salts, McGraw-Hill, New York, 1964. Tanaka, N., H. Ohtuki, and R. Tamamushi (Eds), Ions and Molecules in Solution, Elsevier, Amsterdam, 1983. Tanford, C , The Hydrophobic Effect: Formation of Micelles and Biological Membranes, 2nd ed., John Wiley & Sons, New York, 1980. Tremillon, B., Chemistry in Non-aqueous Solvents, Reidel, Dordrecht, 1974. 1.3 Interionic Interactions
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