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The most extensive investigations on SPs have been carried out on the polymer gels in which a network of long polymer molecules holds the liquid in place and so gives the gel what solidity it has Chemically cross-linked gels can undergo a transition between a collapsed and an expanded state, that is, between a shrunk and a swollen state (Fig 31) The difference between these two states could reach several orders of magnitude This behavior has been very attractive for the applications of the gels as potential actuators, sensors, controllable membranes for separations, and modulators for drug delivery (Osada and Gong, 1998) Studies on the light-responsive gels began as early as the 1970s Van der Veen and Prins (1971) prepared a gel system consisting of a low-molecular-weight (LMW) chrysophenine dye (1) and a water-swollen gel of poly(2-hydroxyethyl methacrylate) cross-linked with ethylene glycol dimethylacylate.

catalysis, electrical mobility, the behaviour of polyelectrolytes, etc. Ion pairs (A+B~) are formed in fused salts through a process in which the cations or anions of the solvent and of the solute exchange positions in the solvent lattice until the cations and anions occupy neighbouring positions. If the solvent is denoted as XY, then this process can be expressed by the scheme:

16

The polymer gel was found to contract upon irradiation of UV light, because the trans cis isomerization causes a reduction in hydrophobicity of the dye, librating the dyes from the polymer chain to the surrounding solution The same type of the photoinduced deformations was also observed in cross-linked poly(methacrylic acid) on which chrysophenine was absorbed (Van der Veen and Prins, 1974) In contrast, adsorption of the positively charged dye, 4-phenylazophenyl trimethylammonium iodide (2), to the cross-linked poly(methacrylic acid) lm led to the reverse of the photoresponsive behavior described earlier (Van der Veen et al, 1974) Swelling occurred upon irradiation of UV light, whereas contraction took place during relaxation in the dark The aqueous polymeric acid gel combined with the positively charged trans form takes on a more hydrophobic and globular conformation.

x + A + Y"

management between the two environments, based on the underlying technologies. For example, with MSVS, moving VMs requires a stop, move, and start, while with the hypervisor that will be a live migration. VMM offers a variety of features, including monitoring and management, some automated configuration features, P2V utilities, grouping functions, and more. VMM is integrated in the Microsoft System Center family of products, offering the advantage of managing both physical and virtual environments. In mid 2006, Microsoft announced its acquisition of Softricity Inc., a provider of application virtualization and dynamic streaming technologies. This technology will allow virtualization within the OS environment, creating the equivalent of virtualized or guest applications as opposed to guest OSs, virtualizing at the registry level, with some level of isolation. Microsoft announced availability of the Softricity SoftGrid application virtualization platform as two planned offerings: SoftGrid for Desktops and SoftGrid for Terminal Services.

( Y X + Y" X + Y"X +Y") +Y" + + + + + X B~X Y"A B "X ^rx + Y"X+ Y~ X + Y~X CY"

After irradiation of UV light, the more soluble cis isomer is formed, causing the dye to drop off the polymer As a result, the polymer relaxes to an extended conformation, and the sample swells..

According to M. Blander the association constant depends on the change in the Gibbs energy, AG, during exchange of a solvent anion Y~, next to a cation of the dissolved salt A + , for an anion of the dissolved salt B~ according to the relationship lnl += ^ (1-2.20)

Compared with the gels sensitive to such stimuli as pH and heat, the studies on the light-responsive gels develop much more slowly There have been few reports concerning the photoinduced changes in shape or volume of the polymer gels for about 30 years, except that Irie and Suzuki et al have respectively done some excellent work on modi cation of the side chains of the gel networks with functional groups other than azobenzenes that either undergo ionization upon irradiation of UV light (Irie and Kungwatchakun, 1995; Ishikawa et al, 1991; Mamada et al, 1990; Irie, 1986) or cause local heating by absorbing energy from visible light (Suzuki et al, 1996; Suzuki and Tanaka, 1990) Recently, a successful strategy to manipulate the swelling response by light has been reported on poly(N-isopropylacrylamide) gels wherein the cross-links contain azobenzene groups.

As a newer entrant into the server virtualization space, Microsoft will still, no doubt, make a huge impact. The initial Virtual Server offering may lack the performance benefits of a hypervisor approach, but has still made strong inroads. This is likely due to the fact that it is available for free, and that it allows Windows users to move into virtualization and start to reap the benefits while staying in the comfort zone of the Windows environment. With the addition of Virtual Machine Manager and Windows Server Virtualization in Longhorn, Microsoft will begin to catch up with the other hypervisor approaches and management tools. The licensing of VHD will create a mini ecosystem around Microsoft virtualization, enabling third parties to succeed in delivering other products, such as advanced management tools for Microsoft and Xen products. It will be interesting to see where the application virtualization goes as well; it may be an area of differentiation, right up the Microsoft alley.