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criterion is the quantity kT/hco, where fi is Planck's constant divided by 2n and co is the angular frequency of vibration At laboratory temperature kT/hco =* 10~13 For the vibration of the solvent shell co kT/h while for the vibration of the electron shell co kT/ft, which means that the electron transfer can be considered as adiabatic Under these conditions, a further simplification is possible as the whole problem can be treated classically, the vibrations of the solvation shell being discussed in terms of a set of classical harmonic oscillations.

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In order to describe properly the electron transfer between the electroactive ion B z+ and the electrode Bz+(l) + e(m)-*B (2 - 1)+ (l) the following assumptions are necessary: (a) The solvation shells of the ions Bz+ and B (2 ~ 1)+ vibrate harmonically with identical frequency co> so that the potential energies of both solvation shells can be expressed by identical mutually shifted parabolas (b) Quantum-mechanical effects need not be considered in the region around the activated complex (in the vicinity of the intersection of the two parabolas) (c) The kinetic energy of the system is identical in the initial and final states (d) Only electrons from the Fermi level in the electrode and from the redox system in the solution in the ground state participate in the electrode reaction (e) The concentrations of the ions Bz+ and B (2 ~ 1)+ are equal to unity.

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Eich M, Wendorff JH, Reck B, Ringsdorf H 1987 Reversible digital and holographic optical storage in polymeric liquid crystal Makromol Chem Rapid Commun 8:59 63 Faul CFJ, Antonetti M 2003 Ionic self assembly: facile synthesis of supramolecular materials Adv Mater 15:673 683 Fiorini C, Prudhomme N, de Veyrac G, Maurin I, Raimond P, Nunzi J M 2000 Molecular migration mechanism for laser induced surface relief grating formation Synth Met 115:121 125 Fischer T, Lasker L, Czapla S, Rubner J, Stumpe J 1997 Interdependence of photo orientation and thermotropic self organization in photochromic liquid crystalline polymers Mol Cryst Liq Cryst 298:213 220 Frey L, Darracq B, Chaput F, Lahlil K, Jonathan JM, Roosen G, Boilot JP, Levy Y 2000 Surface and volume gratings investigated by the moving grating technique in sol gel materials Optics Commun 173:1 16 Fuhrmann T, Wendorff HJ 1997 Optical data storage In: Brostow W, Collyer A, editors.

Hitachi may not have been the first company to offer blade and virtualization solutions, but they are the only ones who are incorporating the knowledge they have gained over 20 years of developing mainframes into their blade and virtualization offerings. With annual revenues of $80 billion worldwide, Hitachi is able to focus resources on their BladeSymphony solutions, leveraging their close partnership with Intel.

The profile of the potential energy Ep of the reacting system in dependence on the reaction coordinate x is shown in Fig 56 The curve denoted as R corresponds to the initial state of the system The coordinates of its minimum, ie the ground state of the system, are xQ(i), 0 The curve for the final state P is shifted by a value corresponding to the difference between the final and initial energies of the electronic subsystem, AEC The coordinate xo(f) corresponds to the minimum on the potential curve for the final state The potential energy of the initial state of the system is given by the equation Ep:i = ^mco2[x-x0(i)]2 (532) (531).

Polymer Liquid Crystals Vol 4 London: Chapman and Hall Fukuda T, Sumaru K, Kimura T, Matsuda H 2001a Observation of optical near eld as photo induced surface relief formation Jpn J Appl Phys 40:L900 L902..

(where m is the effective mass of the vibrating system) and the energy of the final state by the equation P,f = \mco\x - jco(f)]2 + A e (5.3.3)

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